Carbonylation catalyst system

Catalyst system comprising a palladium compound, an acid compound having a pKa>2 measured in water of 18° C. and an non-symmetrical bidentate phosphorous ligand according to:in which the -PR1R2 group is different from the -PR3R4 group and in which X is a divalent organic bridging group, in which...

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Bibliographische Detailangaben
Hauptverfasser: HENK OEVERING,FRANK P. W. AGTERBERG, OTTO E. SIELCKEN
Format: Patent
Sprache:eng
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Beschreibung
Zusammenfassung:Catalyst system comprising a palladium compound, an acid compound having a pKa>2 measured in water of 18° C. and an non-symmetrical bidentate phosphorous ligand according to:in which the -PR1R2 group is different from the -PR3R4 group and in which X is a divalent organic bridging group, in which the shortest direct link between the two phosphorous atoms in the bridging group X consists of a chain of 2-10 carbon atoms and optionally a sulphur or oxygen atom.