Process for catalytic hydrogenation of unsaturated carboxylic acids and carboxylic acid products produced thereby

The present invention provides a method for catalytically hydrogenating an unsaturated carboxylic acid and a carboxylic acid product prepared thereby, the method comprising: reacting a raw material comprising an unsaturated carboxylic acid with hydrogen in a hydrogenation reactor in the presence of...

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Hauptverfasser: YANG ZHONGLU, SU YONGSHENG, CHEN FAZHONG
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creator YANG ZHONGLU
SU YONGSHENG
CHEN FAZHONG
description The present invention provides a method for catalytically hydrogenating an unsaturated carboxylic acid and a carboxylic acid product prepared thereby, the method comprising: reacting a raw material comprising an unsaturated carboxylic acid with hydrogen in a hydrogenation reactor in the presence of a catalyst and a co-catalyst, such that unsaturated groups contained in the unsaturated carboxylic acid are at least partially hydrogenated; wherein the catalyst comprises one or more metals selected from the group consisting of nickel, palladium, platinum, ruthenium, rhodium and alloys thereof, the catalyst is non-supported or supported on a carrier, and the carrier is selected from one or more of the group consisting of activated carbon, aluminum oxide, silicon oxide, aluminosilicate and a molecular sieve; the cocatalyst is perfluorinated sulfonic acid resin. According to the method disclosed by the invention, unsaturated groups in unsaturated carboxylic acid can be hydrogenated with very high efficiency, a targe
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title Process for catalytic hydrogenation of unsaturated carboxylic acids and carboxylic acid products produced thereby
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