Preparation method of MOF (at) Pro HNs hollow mesoporous reticular nano-material, and product and application thereof

The invention relates to a preparation method of an MOF (at) Pro HNs hollow mesoporous reticular nano material as well as a product and application thereof, and belongs to the technical field of preparation of functional materials. The preparation method mainly comprises the following steps: firstly...

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Hauptverfasser:	HAN MENGLIN, XIANG YU, ZHOU JIFENG, JIANG XILE, LI JIANYU, ZHOU XIANJU, HU HONGYUAN, CAI QINGCHI, JIA RUNZE, XIE GUANGXIN, YU YAO, XIE LINLIN, TAO SHENGRONG, HUANG LEYI, DONG WEI, ZHANG WEIQI
Format:	Patent
Sprache:	chi ; eng
Schlagworte:	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOSITIONS BASED THEREON HETEROCYCLIC COMPOUNDS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR PREPARATION OR CHEMICAL WORKING-UP THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	The invention relates to a preparation method of an MOF (at) Pro HNs hollow mesoporous reticular nano material as well as a product and application thereof, and belongs to the technical field of preparation of functional materials. The preparation method mainly comprises the following steps: firstly, mixing Boc-proline, KOH, absolute methanol and DMSO to react, and adding triethylamine and trimethylsilyl trifluoromethanesulfonate in an ice bath to react to obtain proline Pro; then, a DMSO solution of proline pro, a DMSO solution of cobalt acetate tetrahydrate and a DMSO solution of terephthalic acid (H2BDC) are subjected to a heating reaction in an oxygen-free environment, and the MOF (at) Pro HNs hollow mesoporous net-shaped nanometer material is obtained. Cobalt acetate tetrahydrate, TEA and H2BDC are used as raw materials, Boc-proline is complexed, the MOF-coated Pro HNs hollow mesoporous reticular nanometer material with high hydrophilicity, high permeability and high stereoselectivity is prepared, the pr