Fluorescent covalent organic framework material as well as preparation method and application thereof

The invention belongs to the technical field of heavy metal detection, and discloses a fluorescent covalent organic framework material as well as a preparation method and application thereof. The structural formula of the fluorescent covalent organic framework material is shown as follows: # imgabs0...

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Bibliographische Detailangaben
Hauptverfasser:	LYU GUIFEN, WEI XINRUI, GAN JUNLAN, HUANG HUIHUI, JIAN QIQI, ZHANG YALIN, CAI YUTING, CHEN RUI, HE JUN
Format:	Patent
Sprache:	chi ; eng
Schlagworte:	ADHESIVES CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOSITIONS BASED THEREON DYES INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIRCHEMICAL OR PHYSICAL PROPERTIES MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE MEASURING METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS ORGANIC MACROMOLECULAR COMPOUNDS PAINTS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL PHYSICS POLISHES TESTING THEIR PREPARATION OR CHEMICAL WORKING-UP THEIR RELEVANT APPARATUS TRANSPORTING TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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Beschreibung
Zusammenfassung:	The invention belongs to the technical field of heavy metal detection, and discloses a fluorescent covalent organic framework material as well as a preparation method and application thereof. The structural formula of the fluorescent covalent organic framework material is shown as follows: # imgabs0, and the fluorescent covalent organic framework material has an efficient recognition effect on Hg < 2 + >, almost has no fluorescence enhancement or weakening effect on other metal ions, only shows a fluorescence quenching effect on Hg < 2 + >, and has a fluorescence quenching effect on Hg < 2 + >. The concentration of the mercury ions added in the range of 10-100 [mu] M is linearly related to the fluorescence intensity of the fluorescent covalent organic framework material, the fluorescence detection range is 10-100 [mu] M, and the detection limit is 2.43 [mu] M. 本发明属于重金属检测技术领域，公开了一种荧光共价有机框架材料及其制备方法和应用。该荧光共价有机框架材料，其结构式如下所示：#imgabs0#该荧光共价有机框架材料对Hg2+具有高效的识别效应，对于其他金属离子几乎不存在荧光增强或减弱效应，只对于Hg2+显示出荧光猝灭的效应，在10-100μM范围内加入