Chiral binaphthalene macrocyclic aromatic hydrocarbon, derivative, and synthesis method and application of chiral binaphthalene macrocyclic aromatic hydrocarbon

The invention provides chiral binaphthalene macrocyclic aromatic hydrocarbon, a derivative and a synthesis method and application thereof, and belongs to the technical field of synthesis and derivatization of supramolecular macrocycles. On the basis of synthesis and derivatization of chiral binaphth...

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Hauptverfasser: LI CHUNJU, DONG MING, ZHANG XUE, WU WENTING, SUN YUE, JANG CHI-WON, SUN GUANG, ZHANG YUEYI
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention provides chiral binaphthalene macrocyclic aromatic hydrocarbon, a derivative and a synthesis method and application thereof, and belongs to the technical field of synthesis and derivatization of supramolecular macrocycles. On the basis of synthesis and derivatization of chiral binaphthyl macrocyclic aromatic hydrocarbons, a chiral binaphthyl aromatic hydrocarbon monomer is obtained through suziki coupling reaction by taking a dibromo raw material, a series of chiral binaphthyl macrocyclic aromatic hydrocarbons are obtained through reaction by taking the monomer and paraformaldehyde as raw materials, taking halogenated alkane as a solvent and taking lewis acid as a catalyst, and the chiral binaphthyl macrocyclic aromatic hydrocarbons are obtained through further derivatization. The water-soluble derivative of the chiral binaphthalene macrocyclic aromatic hydrocarbon is obtained. The chiral binaphthalene macrocyclic aromatic hydrocarbon with the recognition site, which is synthesized by the invent