Method for preparing MMA (methyl methacrylate) by coal-based route C2 method

The invention discloses a method for preparing MMA (methyl methacrylate) by a coal-based route C2 method, and particularly relates to the field of MMA preparation, which comprises the following steps: mixing a methanol solution of formaldehyde and propionaldehyde according to a molar ratio of 1: 1,...

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Hauptverfasser: DUAN YIRAN, HOU ZHENLIN, HAN ZENGJUN, ZHOU YANG, LIU YONGXIN, YI LIMEI, LU HAIWEI, YU LIANG, PAN YONGFENG, LI ZONGZHOU, RONG QING, LIU YUBIN, ZHANG CHAO, KANG ZHENJIE, NA MINGJUN, GE WEI, SONG HUALEI, ZHAO HAINING
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention discloses a method for preparing MMA (methyl methacrylate) by a coal-based route C2 method, and particularly relates to the field of MMA preparation, which comprises the following steps: mixing a methanol solution of formaldehyde and propionaldehyde according to a molar ratio of 1: 1, and carrying out thermal condensation reaction under the catalytic action of a catalyst to obtain a mixed product containing a water phase and an oil phase; performing oil-water separation on the mixed product to obtain an oil phase which comprises a methanol-MAL mixed solution; methanol is taken additionally, the methanol and the methanol-MAL mixed solution are subjected to an oxidative esterification reaction according to the molar ratio of (3-10): 1, and an MMA crude product is obtained; according to the method, a conventional aqueous solution of formaldehyde is adjusted into a methanol solution of formaldehyde, azeotropy and boiling point temperature difference of methanol and MAL can be effectively separated t