Preparation method of thermosetting polyimide material taking water as solvent

The invention discloses a preparation method of a thermosetting polyimide material only using water as a solvent. The polyimide is prepared from the following raw materials: symmetric dianhydride, asymmetric dianhydride, an active end-capping reagent, symmetric diamine, asymmetric diamine and the li...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: UHEI, WANG HAIYUE, HUANG QIRUI, JIA ZICHEN, LIU CAI, WU SHUPEI
Format: Patent
Sprache:chi ; eng
Schlagworte:
Online-Zugang:Volltext bestellen
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The invention discloses a preparation method of a thermosetting polyimide material only using water as a solvent. The polyimide is prepared from the following raw materials: symmetric dianhydride, asymmetric dianhydride, an active end-capping reagent, symmetric diamine, asymmetric diamine and the like. The specific preparation method comprises the following steps: adding dianhydride and an end-capping reagent into deionized water, and rotating at a constant speed for a certain time by utilizing a magnetic force or a mechanical stirrer at a certain temperature, so that the dianhydride and the end-capping reagent are completely depolymerized into carboxylic acid; cooling to room temperature, adding diamine into the solution, and stirring for a certain time to form a polyimide prepolymer; and putting the obtained prepolymer salt into a closed high-pressure reaction kettle, and carrying out polycondensation reaction on the monomer salt under the conditions of temperature higher than the boiling point of water and