Method for separating arsenic from copper sulfate solution

The invention discloses a method for separating arsenic from a copper sulfate solution. The method for separating arsenic from the copper sulfate solution comprises the steps of pretreatment, oxidation, arsenic removal and aftertreatment, and specifically comprises the following steps: adding water...

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Hauptverfasser: DAI HONGKUN, XU QINGXIN, RUAN MAOGUANG, PENG XUEBIN, LI XIANHONG, ZHANG CHAOWEN, SHI HUIXIAN, ZHAO SHANRONG, MA YULONG, CHEN XIN, SHU DAYONG, XU ZHENGGUO, YAN SEN, HE XIAOCAI, XIE GANG, YANG MEIYAN, DIAO WEIZHI, YAN HUALONG, YANG KUN, ZHI HAIQING, YUAN YE, YANG YI, REN JIUYANG, XU FUSHUN
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention discloses a method for separating arsenic from a copper sulfate solution. The method for separating arsenic from the copper sulfate solution comprises the steps of pretreatment, oxidation, arsenic removal and aftertreatment, and specifically comprises the following steps: adding water into crude copper sulfate for dissolving to obtain a crude copper sulfate solution a; adding an oxidizing agent for reaction to obtain reaction liquid b; adding a dearsenification agent for dearsenification reaction to obtain reaction liquid c; adding a flocculating agent into the reaction liquid c for settling, and performing liquid-solid separation to obtain an arsenic-removed copper sulfate solution and purified residues; the arsenic-removed copper sulfate solution can be crystallized to produce a copper sulfate product or electrodeposited copper; and returning the purified slag to a pyrogenic copper smelting system to recover copper. According to the method, arsenic in the crude copper sulfate solution is effic