Synthesis method of substituted benzoyl isocyanate

The invention discloses a synthetic method of substituted benzoyl isocyanate, and belongs to the technical field of synthesis of pesticide intermediates, the synthetic method comprises the following steps: adding sodium cyanate and a composite catalyst into an organic solvent, heating to 40-60 DEG C...

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Hauptverfasser: WANG ZHENYU, CHEN JUKUI, ZHU ZHANG, ZHANG JUN, LI JIAN, JIANG JINGWEN, SU RUI
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creator WANG ZHENYU
CHEN JUKUI
ZHU ZHANG
ZHANG JUN
LI JIAN
JIANG JINGWEN
SU RUI
description The invention discloses a synthetic method of substituted benzoyl isocyanate, and belongs to the technical field of synthesis of pesticide intermediates, the synthetic method comprises the following steps: adding sodium cyanate and a composite catalyst into an organic solvent, heating to 40-60 DEG C, dropwise adding benzoyl chloride into the organic solvent, heating to 60 DEG C after dropwise adding, stirring at a constant temperature for 3.2-5.5 h, cooling to the room temperature, and filtering to obtain the substituted benzoyl isocyanate. And after the reaction is finished, distilling off the solvent under reduced pressure, and continuously distilling off the substituted benzoyl isocyanate under reduced pressure. Under the composite catalytic action of p-toluenesulfonic acid and heteropoly acid, the purpose of increasing the yield of substituted benzoyl isocyanate is finally achieved, through inspection, the yield reaches 92.5%-95.0%, meanwhile, the reaction efficiency is remarkably improved, finally, effic
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title Synthesis method of substituted benzoyl isocyanate
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