Preparation method and application of organic acid modified aluminum metaphosphate supported nickel-palladium catalyst

The invention discloses a preparation method and application of an organic acid modified aluminum metaphosphate supported nickel-palladium catalyst, the preparation method comprises the following steps: adding a carrier Al (PO3) 3, 4-trifluoromethylsalicylic acid TFMSA, a nickel source and a palladi...

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Hauptverfasser:	XIA LEI, ZHAO YUNPENG, ZHANG YULU, LIU FANGJING, WANG MENGJIE, ZHANG HANBING, WEI XIANYONG, CAO JINGPEI
Format:	Patent
Sprache:	chi ; eng
Schlagworte:	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY CRACKING HYDROCARBON OILS FUELS LUBRICANTS METALLURGY MINERAL WAXES PEAT PERFORMING OPERATIONS PETROLEUM, GAS OR COKE INDUSTRIES PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	The invention discloses a preparation method and application of an organic acid modified aluminum metaphosphate supported nickel-palladium catalyst, the preparation method comprises the following steps: adding a carrier Al (PO3) 3, 4-trifluoromethylsalicylic acid TFMSA, a nickel source and a palladium source into acetone, stirring at room temperature to obtain a suspension, carrying out rotary evaporation to remove the solvent acetone, drying in a vacuum drying oven, and grinding the obtained solid into solid powder by using a mortar; in an inert atmosphere, raising the temperature to a specified temperature in a tubular furnace, and calcining to obtain solid powder; and reducing in an H2 atmosphere at a specified temperature to obtain black solid powder, namely the organic acid modified aluminum metaphosphate supported nickel-palladium catalyst which is marked as NiPd-TFMSA/Al (PO3) 3. The invention also discloses application of the organic acid modified aluminum metaphosphate supported nickel-palladium cata