Catalyst component for olefin polymerization and preparation method and application thereof

The invention relates to an olefin polymerization catalyst, and discloses a catalyst component for olefin polymerization and a preparation method and application thereof. The catalyst component comprises a magnesium element, a titanium element and an internal electron donor, wherein the internal ele...

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Hauptverfasser: LING YONGTAI, XIE JIJIA, CHEN LONG, ZHOU JUNLING, LI, WEILI, LIU YUEXIANG, XIE LUNJIA, GAO FUTANG, ZHAO JIN, MA CHANGYOU, YANG RUI, TAN YANG, REN CHUNHONG, ZHANG XIAOFAN, XIA, XIANZHI, YI ZHUO, DU CHAO, FENG ZAIXING, LIU TAO
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention relates to an olefin polymerization catalyst, and discloses a catalyst component for olefin polymerization and a preparation method and application thereof. The catalyst component comprises a magnesium element, a titanium element and an internal electron donor, wherein the internal electron donor comprises phosphate ester and alpha-cyano succinate and/or substituted alpha-cyano succinate, and the molar ratio of the phosphate ester to the magnesium element is (0.0002-0.002): 1. When the catalyst is used for olefin polymerization, especially propylene polymerization, an obtained polymer has the characteristics of relatively high Z + 1 average molecular weight and good rigidity-toughness balance. 本发明涉及烯烃聚合催化剂,公开了一种烯烃聚合的催化剂组分及其制备方法和用途。本发明的催化剂组分包括镁元素、钛元素和内给电子体;其中,内给电子体包括磷酸酯和α-氰基丁二酸酯和/或取代α-氰基丁二酸酯,磷酸酯与镁元素的摩尔比为0.0002-0.002:1。该催化剂用于烯烃聚合尤其用于丙烯聚合时,所得聚合物具有较高的Z+1均分子量、刚韧平衡性好的特点。