Method for producing dibenzylamine

The invention provides a preparation method of dibenzylamine, which comprises the following steps: adding benzonitrile into a high-pressure reaction kettle, mixing with a reaction solvent, carrying out hydrogenation reaction under the action of a cerium oxide loaded ruthenium-iron bimetallic catalys...

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Hauptverfasser: ZHANG YANWEN, JIA SHENGXUAN, SHU ZHENCAO, ZHANG ZHIBO, YUAN PENG, SUN BO, NIE SHAOCHUN
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creator ZHANG YANWEN
JIA SHENGXUAN
SHU ZHENCAO
ZHANG ZHIBO
YUAN PENG
SUN BO
NIE SHAOCHUN
description The invention provides a preparation method of dibenzylamine, which comprises the following steps: adding benzonitrile into a high-pressure reaction kettle, mixing with a reaction solvent, carrying out hydrogenation reaction under the action of a cerium oxide loaded ruthenium-iron bimetallic catalyst to prepare a reaction crude product, cooling and filtering the catalyst, and rectifying and purifying to obtain a dibenzylamine finished product. The method is mild in reaction condition and high in atom utilization rate, and meets clean and green production requirements. 本发明提供了一种二苄胺的制造方法,通过在高压反应釜中,加入苯甲腈与反应溶剂混合,在氧化铈负载的钌-铁双金属催化剂的作用下进行加氢反应,制得反应粗品,经冷却过滤催化剂后,精馏提纯得到二苄胺成品。该方法反应条件温和、原子利用率高,符合清洁、绿色生产要求。
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title Method for producing dibenzylamine
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