Method for producing dibenzylamine
The invention provides a preparation method of dibenzylamine, which comprises the following steps: adding benzonitrile into a high-pressure reaction kettle, mixing with a reaction solvent, carrying out hydrogenation reaction under the action of a cerium oxide loaded ruthenium-iron bimetallic catalys...
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creator | ZHANG YANWEN JIA SHENGXUAN SHU ZHENCAO ZHANG ZHIBO YUAN PENG SUN BO NIE SHAOCHUN |
description | The invention provides a preparation method of dibenzylamine, which comprises the following steps: adding benzonitrile into a high-pressure reaction kettle, mixing with a reaction solvent, carrying out hydrogenation reaction under the action of a cerium oxide loaded ruthenium-iron bimetallic catalyst to prepare a reaction crude product, cooling and filtering the catalyst, and rectifying and purifying to obtain a dibenzylamine finished product. The method is mild in reaction condition and high in atom utilization rate, and meets clean and green production requirements.
本发明提供了一种二苄胺的制造方法,通过在高压反应釜中,加入苯甲腈与反应溶剂混合,在氧化铈负载的钌-铁双金属催化剂的作用下进行加氢反应,制得反应粗品,经冷却过滤催化剂后,精馏提纯得到二苄胺成品。该方法反应条件温和、原子利用率高,符合清洁、绿色生产要求。 |
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本发明提供了一种二苄胺的制造方法,通过在高压反应釜中,加入苯甲腈与反应溶剂混合,在氧化铈负载的钌-铁双金属催化剂的作用下进行加氢反应,制得反应粗品,经冷却过滤催化剂后,精馏提纯得到二苄胺成品。该方法反应条件温和、原子利用率高,符合清洁、绿色生产要求。</description><language>chi ; eng</language><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS ; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; CHEMISTRY ; METALLURGY ; ORGANIC CHEMISTRY ; PERFORMING OPERATIONS ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; THEIR RELEVANT APPARATUS ; TRANSPORTING</subject><creationdate>2024</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20240426&DB=EPODOC&CC=CN&NR=117924095A$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20240426&DB=EPODOC&CC=CN&NR=117924095A$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>ZHANG YANWEN</creatorcontrib><creatorcontrib>JIA SHENGXUAN</creatorcontrib><creatorcontrib>SHU ZHENCAO</creatorcontrib><creatorcontrib>ZHANG ZHIBO</creatorcontrib><creatorcontrib>YUAN PENG</creatorcontrib><creatorcontrib>SUN BO</creatorcontrib><creatorcontrib>NIE SHAOCHUN</creatorcontrib><title>Method for producing dibenzylamine</title><description>The invention provides a preparation method of dibenzylamine, which comprises the following steps: adding benzonitrile into a high-pressure reaction kettle, mixing with a reaction solvent, carrying out hydrogenation reaction under the action of a cerium oxide loaded ruthenium-iron bimetallic catalyst to prepare a reaction crude product, cooling and filtering the catalyst, and rectifying and purifying to obtain a dibenzylamine finished product. The method is mild in reaction condition and high in atom utilization rate, and meets clean and green production requirements.
本发明提供了一种二苄胺的制造方法,通过在高压反应釜中,加入苯甲腈与反应溶剂混合,在氧化铈负载的钌-铁双金属催化剂的作用下进行加氢反应,制得反应粗品,经冷却过滤催化剂后,精馏提纯得到二苄胺成品。该方法反应条件温和、原子利用率高,符合清洁、绿色生产要求。</description><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS</subject><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</subject><subject>CHEMISTRY</subject><subject>METALLURGY</subject><subject>ORGANIC CHEMISTRY</subject><subject>PERFORMING OPERATIONS</subject><subject>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</subject><subject>THEIR RELEVANT APPARATUS</subject><subject>TRANSPORTING</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2024</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZFDyTS3JyE9RSMsvUigoyk8pTc7MS1dIyUxKzauqzEnMzcxL5WFgTUvMKU7lhdLcDIpuriHOHrqpBfnxqcUFicmpeakl8c5-hobmlkYmBpamjsbEqAEAyS4mUw</recordid><startdate>20240426</startdate><enddate>20240426</enddate><creator>ZHANG YANWEN</creator><creator>JIA SHENGXUAN</creator><creator>SHU ZHENCAO</creator><creator>ZHANG ZHIBO</creator><creator>YUAN PENG</creator><creator>SUN BO</creator><creator>NIE SHAOCHUN</creator><scope>EVB</scope></search><sort><creationdate>20240426</creationdate><title>Method for producing dibenzylamine</title><author>ZHANG YANWEN ; JIA SHENGXUAN ; SHU ZHENCAO ; ZHANG ZHIBO ; YUAN PENG ; SUN BO ; NIE SHAOCHUN</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_CN117924095A3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>chi ; eng</language><creationdate>2024</creationdate><topic>ACYCLIC OR CARBOCYCLIC COMPOUNDS</topic><topic>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</topic><topic>CHEMISTRY</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><topic>PERFORMING OPERATIONS</topic><topic>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</topic><topic>THEIR RELEVANT APPARATUS</topic><topic>TRANSPORTING</topic><toplevel>online_resources</toplevel><creatorcontrib>ZHANG YANWEN</creatorcontrib><creatorcontrib>JIA SHENGXUAN</creatorcontrib><creatorcontrib>SHU ZHENCAO</creatorcontrib><creatorcontrib>ZHANG ZHIBO</creatorcontrib><creatorcontrib>YUAN PENG</creatorcontrib><creatorcontrib>SUN BO</creatorcontrib><creatorcontrib>NIE SHAOCHUN</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>ZHANG YANWEN</au><au>JIA SHENGXUAN</au><au>SHU ZHENCAO</au><au>ZHANG ZHIBO</au><au>YUAN PENG</au><au>SUN BO</au><au>NIE SHAOCHUN</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Method for producing dibenzylamine</title><date>2024-04-26</date><risdate>2024</risdate><abstract>The invention provides a preparation method of dibenzylamine, which comprises the following steps: adding benzonitrile into a high-pressure reaction kettle, mixing with a reaction solvent, carrying out hydrogenation reaction under the action of a cerium oxide loaded ruthenium-iron bimetallic catalyst to prepare a reaction crude product, cooling and filtering the catalyst, and rectifying and purifying to obtain a dibenzylamine finished product. The method is mild in reaction condition and high in atom utilization rate, and meets clean and green production requirements.
本发明提供了一种二苄胺的制造方法,通过在高压反应釜中,加入苯甲腈与反应溶剂混合,在氧化铈负载的钌-铁双金属催化剂的作用下进行加氢反应,制得反应粗品,经冷却过滤催化剂后,精馏提纯得到二苄胺成品。该方法反应条件温和、原子利用率高,符合清洁、绿色生产要求。</abstract><oa>free_for_read</oa></addata></record> |
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subjects | ACYCLIC OR CARBOCYCLIC COMPOUNDS CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING |
title | Method for producing dibenzylamine |
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