Method for synthesizing naphthyl-containing propargyl fluorine compound from sulfur hexafluoride

The invention discloses a method for synthesizing a naphthyl-containing propargyl fluorine compound from sulfur hexafluoride, and belongs to the technical field of organic intermediate synthesis. The synthesis method comprises the following steps: putting a naphthyl-containing propargyl alcohol comp...

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Hauptverfasser: ZHAO YUE, ZHU SHAN, XIE LANGUI, XU ZHENGJIE, ZHU FENG, CHEN YIFENG, SONG YUMEI, HANG CHEN, ZHANG LIJIAO, MA FENGXIANG
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention discloses a method for synthesizing a naphthyl-containing propargyl fluorine compound from sulfur hexafluoride, and belongs to the technical field of organic intermediate synthesis. The synthesis method comprises the following steps: putting a naphthyl-containing propargyl alcohol compound, a photocatalyst, alkali and a solvent into a reaction container, introducing sulfur hexafluoride gas, and reacting under the condition of blue light illumination to obtain the naphthyl-containing propargyl fluorine compound. Compared with other methods for synthesizing propargyl fluoride compounds, the method disclosed by the invention has the beneficial effects that the reaction conditions are mild, the used reaction raw materials (including propargyl alcohol and N, N-diisopropylethylamine) are cheap and easy to obtain, and SF6 gas can be well utilized with lower energy under the irradiation of blue light. The reaction has the characteristics of low cost, low energy consumption, environmental friendliness an