Preparation method of trifunctional aziridine cross-linking agent

The invention discloses a preparation method of a trifunctional aziridine cross-linking agent, which comprises the following steps: S1, carrying out Michael addition reaction on a compound 1 and a compound 2 to obtain an intermediate; s2, mixing the intermediate in the step S1, alkali I, a copper ca...

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Hauptverfasser: LI YIBIAO, MA WEIZHENG, LIU JIEWEI, DENG ENZE, XU YANGHAO, FENG YINGQI, XIE SIJIE, HONG HUANLIANG, CHEN ZEBIN
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention discloses a preparation method of a trifunctional aziridine cross-linking agent, which comprises the following steps: S1, carrying out Michael addition reaction on a compound 1 and a compound 2 to obtain an intermediate; s2, mixing the intermediate in the step S1, alkali I, a copper catalyst, an organic amine ligand and a solvent I, and carrying out cyclization reaction to obtain the trifunctional aziridine cross-linking agent, wherein the structural formulas of the compound 1, the compound 2, the intermediate and the trifunctional aziridine cross-linking agent are as follows: # imgabs0 # R is selected from at least one of hydroxyl, halogen, a methanesulfonate group, a trifluoromethanesulfonic acid group or p-toluenesulfonyloxy. According to the method, the aziridine cross-linking agent is prepared by adopting a free radical nitrogen cyclization strategy, the use of a high-toxicity chemical aziridine is avoided, and the method has the advantages of mild reaction conditions, simple post-treatment