Preparation method of citral

The invention provides a preparation method of citral, which comprises the following steps: controlling the key component isopentenoic acid in a citral intermediate composition within the range of 10-2000ppm, and then carrying out thermal rearrangement reaction to prepare a citral product. According...

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Bibliographische Detailangaben
Hauptverfasser: ZHANG HONGTAO, LIU YINGJUN, LI YUAN, PANG JICHANG, WANG LIANFANG, SHEN YUANWEI, MENG MENG
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention provides a preparation method of citral, which comprises the following steps: controlling the key component isopentenoic acid in a citral intermediate composition within the range of 10-2000ppm, and then carrying out thermal rearrangement reaction to prepare a citral product. According to the method, the selectivity of isomerization side reaction can be effectively reduced, and the yield of the final product citral is increased to 95% or above. 本发明提供了一种柠檬醛的制备方法,通过控制柠檬醛中间体组合物中关键组分异戊烯酸在10~2000ppm范围内,之后进行热重排反应,制备得到柠檬醛产品。本发明的方法可有效降低异构副反应的选择性,提升最终产品柠檬醛的收率至95%以上。