Method and application of C60 modified black phosphorus modified aluminum-supported palladium-based catalyst

The invention discloses a method and application of a C60 modified black phosphorus modified aluminum-supported palladium-based catalyst. The method comprises the following steps: S1, preparing black phosphorus micro powder; s2, preparing a nano black phosphorus dispersion liquid; s3, preparing a na...

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Hauptverfasser: XIE CHUAN, ZENG FANZHANG, LIU CHANG, WANG JIANNAN, ZHOU MIN
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention discloses a method and application of a C60 modified black phosphorus modified aluminum-supported palladium-based catalyst. The method comprises the following steps: S1, preparing black phosphorus micro powder; s2, preparing a nano black phosphorus dispersion liquid; s3, preparing a nano black phosphor-C60 dispersion liquid; s4, modifying an aluminum-supported palladium-based catalyst; and S5, catalyzing anthraquinone hydrogenation by using the modified aluminum-supported palladium-based catalyst to prepare hydrogen peroxide. The method has the advantages of mild conditions, simplicity in operation, low cost, large-scale preparation and the like, and the obtained modified aluminum-supported palladium-based catalyst or Pd/Al2O3-BP/C60 is high in activity, stable in hydrogen efficiency and long in service life in a reaction for preparing hydrogen peroxide through anthraquinone hydrogenation. 本发明公开了一种C60修饰的黑磷改性铝载钯基催化剂的方法及应用。涉及以下步骤:S1、制备黑磷微粉;S2、制备纳米黑磷分散液;S3、制备纳米黑磷-C60分散液;S4、改性铝载钯基催化剂;S5、利用改性铝载钯基催化剂催