PolyEDOT with side chain containing free radicals of nitrogen and oxygen as well as preparation method and application of polyEDOT

The invention discloses poly (EDOT) with a side chain containing free radicals of nitroxide, which has a structure as shown in the following formula I. The invention also discloses a preparation method of the poly (EDOT) and an application of the poly (EDOT) as an electrochemical oxidation catalyst. The PDOT-TEMPO prepared by the invention has catalytic activity similar to that of TEMPO, and has good catalytic oxidation performance when being applied to a reaction for preparing aldehyde by electrocatalytic oxidation of alcohol. PDOT-TEMPO is attached to the electrode and is easy to separate after catalytic reaction, the electrode can be directly taken out, and the electrode can be repeatedly used after being washed. # imgabs0 # 本发明公开了一种侧链含氮氧自由基的聚EDOT，具有如下式I所示的结构，并且公开了其制备方法，以及作为电化学氧化催化剂的应用。本发明制得的PDOT-TEMPO具有类似TEMPO的催化活性，将其用于醇的电催化氧化制备醛的反应，具有良好的催化氧化性能。而且PDOT-TEMPO附着在电极上，催化反应后容易分离，直接取出电极即可，冲洗后可反复多次使用。#imgabs0#