Preparation method of oil-resistant and seawater-resistant polyurethane-based composite material

The invention provides a preparation method of an oil-resistant and seawater-resistant polyurethane-based composite material, which comprises the following steps: preparing an isocyanate-terminated prepolymer from polycarbonate diol, isophorone dichloride and bis (hydroxymethyl) butyric acid; then n...

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Bibliographische Detailangaben
Hauptverfasser: WANG WEI, GAO LE, XU RAN, RUAN ZIYI, ZHANG BINGQI, AI JING, ZHAO ZIJI, WEI JIAGUI, LIU YUXI, HUANG JIAQIANG, DIAO DONGDONG
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention provides a preparation method of an oil-resistant and seawater-resistant polyurethane-based composite material, which comprises the following steps: preparing an isocyanate-terminated prepolymer from polycarbonate diol, isophorone dichloride and bis (hydroxymethyl) butyric acid; then nano particles or precursors of the nano particles are added for in-situ polymerization to prepare nano particle/polycarbonate type waterborne polyurethane hybrid resin, the nano particle/polycarbonate type waterborne polyurethane hybrid resin is compounded with liquid crystal polymer fibers, and the flexible composite material is prepared through a coating process. The prepared oil-resistant and seawater-resistant polyurethane-based composite material can be applied to underwater oil storage bags, such as storage of crude oil and product oil, development of ocean (marginal) oil fields, long-term storage and replenishment of island fuel and the like. The high and low temperature performance is excellent, and the usa