Treatment method of acid-containing acidic wastewater in crude selenium production process

The invention discloses a method for treating acid-containing acidic wastewater in a crude selenium production process, which comprises the following steps: adding a reducing agent into the acid-containing acidic wastewater, and carrying out oxidation-reduction reaction to obtain copper tellurium sl...

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Hauptverfasser: YUAN JIE, LIU JIACHEN, GUO KAISHI, ZHU CHUNLIANG, LI XIN, YOU JUN, LI YUDONG, SUN XINGHUA, HE JIAN, YUAN RUI, KONG DESONG, ZHANG JIRUN, ZHANG SHANGFA, LI YING, DONG JINGCHENG, XU YONG
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention discloses a method for treating acid-containing acidic wastewater in a crude selenium production process, which comprises the following steps: adding a reducing agent into the acid-containing acidic wastewater, and carrying out oxidation-reduction reaction to obtain copper tellurium slag and decoppered liquid; detecting the mass concentration of chloride ions in the copper-removed liquid; and when the mass concentration of the chloride ions in the copper-removed liquid is 5-20 g/L, returning the copper-removed liquid to the chlorination and selenium removal treatment process to be used as leaching acid and a chloride ion additive to perform chlorination and selenium removal treatment on the copper-removed sludge. According to the method, the reducing agent is added into the acid-containing acidic wastewater to reduce the copper and the tellurium, so that the copper and the tellurium in the acid-containing acidic wastewater are recovered, and the copper-removed liquid is returned to the chlorinat