Method for preparing nanoscale hydrogen bond organic framework and composite material thereof based on mechanical ball milling method

The invention relates to a method for synthesizing a hydrogen bond organic framework and a composite material thereof by utilizing a mechanical ball milling method. The mechanical ball milling method is an environment-friendly choice, and compared with a traditional solvent preparation method, the mechanical ball milling method has the advantages that the use of a solvent can be reduced to the minimum extent, the subsequent desolventizing step of a solution method is effectively avoided, and the mechanical ball milling method has the advantages in the aspects of sustainability and high efficiency. And meanwhile, the influence of solvent molecules on the structure can be avoided to the greatest extent, so that precise construction of the HOF molecular module is realized, and the method has important significance for realizing predictable gridding synthesis. 本发明涉及利用机械球磨法合成氢键有机框架及其复合材料的方法。本发明的机械球磨法是一种环境友好的选择，与传统的溶剂制备法相比，能最少程度地减少溶剂的使用，且有效避免溶液法后续脱溶剂步骤，在可持续性、高效性方面具有优势。同时能够最大化地避免溶剂分子对于结构的影响，从而实现HOF分子模块的精准构建，对于实现可预测的