Method for preparing normal aldehyde through alpha-olefin hydroformylation
The invention provides a method for preparing normal aldehyde through hydroformylation of alpha-olefin, a preparation method of a heterogeneous catalyst, a heterogeneous catalyst composition and application of the heterogeneous catalyst composition to preparation of normal aldehyde through hydroform...
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creator | ZHANG XIANGJIE YAN TAO CAO ZHI WAN HONGLIU YANG YONG HOU HUAMING LI YONGWANG GONG NENGFENG |
description | The invention provides a method for preparing normal aldehyde through hydroformylation of alpha-olefin, a preparation method of a heterogeneous catalyst, a heterogeneous catalyst composition and application of the heterogeneous catalyst composition to preparation of normal aldehyde through hydroformylation reaction of alpha-olefin. The invention also relates to the use of the catalyst for increasing the normal/isomeric ratio of normal aldehyde to isomeric aldehyde in an aldehyde product prepared by hydroformylation of alpha-olefin to 70 or more. According to the normal aldehyde preparation method disclosed by the invention, the ligand for modifying the catalyst is mixed with the solvent, the catalyst and the reaction raw materials, and the catalyst modification and the catalytic reaction are synchronously carried out in the reaction process, so that the defect that the catalytic ligand is easy to fall off in the conventional process is avoided, and high n-iso-ratio product distribution and high straight-chain |
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The invention also relates to the use of the catalyst for increasing the normal/isomeric ratio of normal aldehyde to isomeric aldehyde in an aldehyde product prepared by hydroformylation of alpha-olefin to 70 or more. According to the normal aldehyde preparation method disclosed by the invention, the ligand for modifying the catalyst is mixed with the solvent, the catalyst and the reaction raw materials, and the catalyst modification and the catalytic reaction are synchronously carried out in the reaction process, so that the defect that the catalytic ligand is easy to fall off in the conventional process is avoided, and high n-iso-ratio product distribution and high straight-chain</abstract><oa>free_for_read</oa></addata></record> |
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subjects | ACYCLIC OR CARBOCYCLIC COMPOUNDS CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY METALLURGY ORGANIC CHEMISTRY PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING |
title | Method for preparing normal aldehyde through alpha-olefin hydroformylation |
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