Porous organic polymer containing chiral phosphorus-sulfur ligand as well as preparation method and application of porous organic polymer

The invention provides a porous organic polymer containing a chiral phosphorus-sulfur ligand as well as a preparation method and application thereof, and the method comprises the following steps: adding chiral phosphorus-sulfur ligand molecules as shown in a formula I, divinyl benzene, styrene and a...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Hauptverfasser:	LU LIANGQIU, SHI BIN, WANG ZETIAN, XIAO WENJING, WANG LIANG
Format:	Patent
Sprache:	chi ; eng
Schlagworte:	AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G APPARATUS THEREFOR CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOSITIONS BASED THEREON COMPOSITIONS OF MACROMOLECULAR COMPOUNDS GENERAL METHODS OF ORGANIC CHEMISTRY GENERAL PROCESSES OF COMPOUNDING HETEROCYCLIC COMPOUNDS MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR PREPARATION OR CHEMICAL WORKING-UP THEIR RELEVANT APPARATUS TRANSPORTING WORKING-UP
Online-Zugang:	Volltext bestellen
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	The invention provides a porous organic polymer containing a chiral phosphorus-sulfur ligand as well as a preparation method and application thereof, and the method comprises the following steps: adding chiral phosphorus-sulfur ligand molecules as shown in a formula I, divinyl benzene, styrene and a polymerization initiator into a pore-forming solvent, and carrying out polymerization reaction at the temperature of 60-120 DEG C, the porous organic polymer is obtained after the pore-forming solvent is removed, R1 is a mono-substituent group or a multi-substituent group, and each substituent group is selected from one of H, methoxyl, vinyl or vinyl phenyl; r2 is a mono-substituent group or a multi-substituent group, and each substituent group is selected from one of H, methoxyl, vinyl or vinyl phenyl; r3 is selected from one of H, vinyl or vinyl phenyl; r1, R2 and R3 at least comprise one vinyl group or vinyl phenyl group. The method provided by the invention is used for solving the problems of high recovery cos