Long-chain alkyl fluorine-containing vinyl silicone oil and preparation method thereof

The preparation method comprises the following steps: (1) adding long-chain alkoxy siloxane, a fluorine-containing cyclosiloxane monomer, a vinyl-containing siloxane monomer, a methyl cyclosiloxane monomer and an end-capping reagent into a reaction kettle provided with a thermometer, a stirrer and a...

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Bibliographische Detailangaben
Hauptverfasser: LI HUI, CHEN YU, LI TONGCHENG
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The preparation method comprises the following steps: (1) adding long-chain alkoxy siloxane, a fluorine-containing cyclosiloxane monomer, a vinyl-containing siloxane monomer, a methyl cyclosiloxane monomer and an end-capping reagent into a reaction kettle provided with a thermometer, a stirrer and a reflux condensation device, setting the stirring speed to be 300-600r/min, stirring for 30-60 minutes, and carrying out heat preservation for 30-60 minutes, thereby obtaining the long-chain alkyl fluorine-containing vinyl silicone oil. Stirring for 10-20 minutes, adding a catalyst, heating to 80-85 DEG C, and carrying out hydrolytic condensation on the system under the action of the catalyst; (2) after reacting for 2-4 hours, heating the reaction system to 130-145 DEG C, and keeping the temperature to react for 6-8 hours; and (3) after the ring-opening polymerization reaction is finished, cooling to neutralize the catalyst, filtering to neutralize the generated salt, and then removing small molecule products in va