Non-doped device of d-f transition rare earth complex

The invention relates to an electroluminescent material and a non-doped electroluminescent device made of the electroluminescent material. The electroluminescent device comprises a cathode, an anode and a luminescent layer located between the cathode and the anode, and the luminescent layer is composed of a luminescent d-f transition Ce (III) complex or Eu (II) complex. The luminescent d-f transition Ce (III) complexes have one or more Ce < 3 + > ions as central luminescent ions and ligands that form coordination bonds with the Ce < 3 + > ions, and the first coordination layer around these Ce < 3 + > ions has 3 to 15 coordination atoms, including one or more of C, N, O, F, Cl, Br, I. The non-doped device has better electroluminescent performance than a same doped device, and meanwhile, the manufacturing cost is lower. 一种电致发光材料及采用该电致发光材料制造的非掺杂电致发光器件。所述电致发光器件包括阴极、阳极，以及位于所述阴极和所述阳极之间的发光层，所述发光层由发光的d-f跃迁Ce(III)配合物或Eu(II)配合物组成；所述发光的d-f跃迁Ce(III)配合物具有一个或者多个Ce3+离子作为中心发光离子以及与Ce3+离子形成配位键的配体，且这些Ce3+离子周围的第一配位层具有3-15个配位原子，所