Phosphorus-nitrogen reactive flame retardant as well as preparation method and application thereof

The invention relates to a phosphorus-nitrogen reactive flame retardant and a preparation method and application thereof.The preparation method comprises the following steps that a DOPO solution and a maleic anhydride solution serve as raw materials, and a product DOPO-MA is prepared through an addi...

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Hauptverfasser: RUAN GUOQIAO, CAO KAI, FANG KAI, HE JIANWU, LIU HANSHUI, LIAO FEIYUN, XIE CHENGYIN, RUAN YINGQUAN
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention relates to a phosphorus-nitrogen reactive flame retardant and a preparation method and application thereof.The preparation method comprises the following steps that a DOPO solution and a maleic anhydride solution serve as raw materials, and a product DOPO-MA is prepared through an addition reaction; the preparation method comprises the following steps: by taking DOPO-MA and diethanol amine as raw materials, carrying out ring-opening reaction in an organic solvent to prepare an intermediate DOPO-MAN; and reacting the intermediate DOPO-MAN with ethylene glycol diglycidyl ether under the condition of 110 to 120 DEG C, so as to prepare the phosphorus-nitrogen reactive flame retardant. Compared with a single-element flame retardant, the phosphorus-nitrogen type flame retardant provided by the invention has more excellent flame retardant property, does not contain halogen and does not cause pollution to the environment, and the flame-retardant modified polyurethane rigid foam prepared from the flame r