Method for preparing composite catalyst for vinyl chloride synthesis by utilizing ruthenium trichloride waste

The invention discloses a method for preparing a composite catalyst for vinyl chloride synthesis by utilizing ruthenium trichloride waste, which comprises the following steps: by taking waste ruthenium trichloride generated in the production of trimethylpyruvic acid as a main raw material, carrying...

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Hauptverfasser: BIAN PINGGUAN, LI JIERUI, LI JUNQI, SHU CHEN, FENG XIAOQIN, PEI FENG, ZHENG KAI, CHEN XIAOHU, XIAO RENGUI, CAO YUNCHAO
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creator BIAN PINGGUAN
LI JIERUI
LI JUNQI
SHU CHEN
FENG XIAOQIN
PEI FENG
ZHENG KAI
CHEN XIAOHU
XIAO RENGUI
CAO YUNCHAO
description The invention discloses a method for preparing a composite catalyst for vinyl chloride synthesis by utilizing ruthenium trichloride waste, which comprises the following steps: by taking waste ruthenium trichloride generated in the production of trimethylpyruvic acid as a main raw material, carrying out wet grinding and solid-liquid separation to obtain a ruthenium trichloride-containing dissolution liquid, adding dilithium tetrachlorocuprate into the dissolution liquid, and carrying out solid-liquid separation to obtain a composite catalyst; adjusting the mass ratio of ruthenium trichloride to dilithium cuprate tetrachlorohydrate in the solution to (0.1-0.5): (5-8), adding activated carbon into the adjusted solution, soaking, and drying to obtain the catalyst for vinyl chloride synthesis; the invention discloses a calcium carbide method vinyl chloride synthesis foreground converter. The method provided by the invention realizes recycling of the dangerous ruthenium trichloride waste. 本发明公开了一种利用三氯化钌废弃物制备氯乙烯合成用复
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subjects ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title Method for preparing composite catalyst for vinyl chloride synthesis by utilizing ruthenium trichloride waste
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