Coordinated luminescent photochromic glass as well as preparation method and application thereof

The invention discloses harmonious luminescent photochromic glass, which is prepared from the following raw materials in percentage by mole: 10 to 20 percent of ZnO, 5 to 15 percent of Ga2O3, 45 to 60 percent of SiO2, 15 to 25 percent of LiCO3, 0.1 to 5 percent of MnO and 1 percent of Sb2O3. According to the glass transparent medium prepared in the invention, under 365nm excitation, with the increase of MnO doping concentration, the light emitting color of the glass is changed from yellow light to red light, an obvious color changing effect can be caused through semiconductor green laser irradiation, bleaching can be carried out through heat assistance, and the glass transparent medium shows potential application in the aspects of laser glass, anti-counterfeiting and optical storage. 本发明公开了一种可协调发光变色玻璃，包括按以下摩尔百分比的原料：ZnO：10～20％、Ga2O3：5～15％、SiO2：45～60％、LiCO3：15～25％、MnO：0.1～5％、Sb2O3：1％。本发明中制备的玻璃透明介质，在365nm激发下，随着MnO掺杂浓度的增加，玻璃的发光颜色从黄光变成了红光，通过半导体绿色激光辐照能够引起明显的变色效应，且能通过热辅助进行漂白，在激光玻璃、防伪、光存储方面展示出潜在的应用。