Preparation method of 50K carbon fiber precursor, precursor and carbon fiber

The invention relates to a preparation method of a 50K carbon fiber precursor, the precursor and a carbon fiber, the preparation method comprises the following steps: (1) acrylonitrile, methyl acrylate and itaconic acid are subjected to a water phase suspension polymerization reaction to obtain a po...

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Hauptverfasser: ZHANG HAI'OU, ZHAO YUNFENG, SHAN XIN, LANG JIANHUI, GUO JIADONG, WANG YU, JU ZHANHUI, WEI LUYAO, LI KAI, JIANG YANBO, CHEN HAO, CHEN HAIJUN, WANG LIWEI, WANG HUI, LYU HONGYU, MAO BINGQI
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention relates to a preparation method of a 50K carbon fiber precursor, the precursor and a carbon fiber, the preparation method comprises the following steps: (1) acrylonitrile, methyl acrylate and itaconic acid are subjected to a water phase suspension polymerization reaction to obtain a polymer, the polymer is terminated through a chelation reaction, and then filtering and drying are performed to obtain a powdery polymer; (2) dissolving the powdery polymer in DMAC (dimethylacetamide) to prepare a spinning solution; (3) enabling the spinning solution prepared in the step (2) to pass through a spinneret plate with the hole number of 49500-50500, spraying at the speed of 13-53m/min, feeding into a coagulating bath, forming to obtain nascent fibers, and washing, oiling, drying, drafting and shaping the nascent fibers to obtain protofilaments; the pressure of the spinneret plate in the step (3) is 800-1600kPa, so that the CV value of the filament density of a monofilament passing through any spinneret pl