Hierarchical porous MOFs material containing CuRu bimetal and preparation method and application thereof

The invention discloses a hierarchical porous MOFs (Metal-Organic Frameworks) material containing CuRu bimetals as well as a preparation method and application of the hierarchical porous MOFs material. The chemical formula of the hierarchical porous MOFs material containing the CuRu bimetal is [Cu < 3-x > Rux (BTC) 2Ix] n, and the formula is as follows: 0.03 lt; xlt; 0.15, and n is gt; i is at least two of Cl , NO3 , Ac and OH . According to the invention, Ru < 3 + > is introduced into a Cu-BTC framework metal node, so that a Cu < 2 + > unsaturated site at the metal node is replaced by Ru < 3 + >, the MOFs material containing CuRu bimetals and containing a Cu-Cu, Cu-Ru and/or Ru-Ru structure is formed, and meanwhile, the MOFs material is also provided with mesopores, and is a hierarchical pore MOFs material. The hierarchical porous MOFs material containing CuRu bimetals is a heterogeneous catalyst, and the separation efficiency and the catalytic activity are remarkably improved. 本发明公开了一种含有CuRu双金属