Silicon center chiral molecular compound and preparation method and application thereof
The invention belongs to the technical field of organic synthesis, and particularly relates to a silicon center chiral molecular compound and a preparation method and application thereof. According to the preparation method of the silicon center chiral molecular compound, transition metal does not n...
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Format: | Patent |
Sprache: | chi ; eng |
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Zusammenfassung: | The invention belongs to the technical field of organic synthesis, and particularly relates to a silicon center chiral molecular compound and a preparation method and application thereof. According to the preparation method of the silicon center chiral molecular compound, transition metal does not need to be used as a catalyst, reaction can be carried out under mild conditions, the advantages of being environmentally friendly, low in cost, wide in substrate selectivity and mild in reaction condition are achieved, and the yield and selectivity of the obtained product are high; and the prepared product simultaneously has two chiral centers of carbon and silicon, is novel in structure, can be converted into a silicon-containing chiral ligand, a silicon-containing chiral drug, an organic photoelectric functional material and the like through a simple method, and has a relatively good application prospect.
本发明属于有机合成技术领域,具体涉及一种硅中心手性分子化合物及其制备方法与应用。所述硅中心手性分子化合物的制备方法无需使用过渡金属作为催化剂,可在较温和的条件下进行反应,具有绿色环保、成本低、底物选择性广、反应条件温和 |
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