Poly (gamma-thiobutyrolactone)

The invention relates to poly (gamma-thiobutyrolactone). The invention discloses a compound as shown in a formula (I). The invention also discloses a high-molecular compound which is prepared by the following preparation method which comprises the following step: in an organic solvent, in the presen...

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Hauptverfasser: HONG MIAO, SUN YANGYANG, YUAN PENGJUN
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention relates to poly (gamma-thiobutyrolactone). The invention discloses a compound as shown in a formula (I). The invention also discloses a high-molecular compound which is prepared by the following preparation method which comprises the following step: in an organic solvent, in the presence of a main catalyst, carrying out polymerization reaction on the compound as shown in the formula (II), so as to obtain the high-molecular compound, the main catalyst is one or more of phosphazene base, guanidine organic base, amidine organic base, N-heterocyclic carbene organic base and N-heterocyclic olefin organic base. The number-average molecular weight and purity of the poly (gamma-thiobutyrolactone) prepared by the preparation method disclosed by the invention are remarkably improved, and the poly (gamma-thiobutyrolactone) has relatively strong solvent corrosion resistance, relatively excellent mechanical properties, surface properties and the like, and has excellent degradability. 本发明涉及一种聚(γ-硫代丁内酯)。本发明公开了