双吡啶基多孔有机笼、笼衍生的共价有机框架及应用

本发明涉及多孔有机功能材料领域，提供了一种双吡啶基多孔有机笼、笼衍生的共价有机框架及应用，采用了BPDDP作为合成子，环己二胺，联苯胺和5,5'-二氨基-2,2'-联吡啶分别作为连接体合成了BPPOC以USTB-1和USTB-2。BPPOC通过亚胺键交换作用，从笼中环己二胺转化为COFs中的联苯胺和5,5'-二氨基-2,2'-联吡啶成功地转化为同结构的USTB-1c和USTB-2c。本发明的BPPOC对碘蒸汽气的吸附量打破了多孔有机笼类材料吸附值的最高记录。与直接合成的USTB-1和USTB-2相比，通过有机笼转化而来的USTB-1c和USTB-2c具有...

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Format:	Patent
Sprache:	chi
Schlagworte:	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOSITIONS BASED THEREON HETEROCYCLIC COMPOUNDS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC CHEMISTRY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR PREPARATION OR CHEMICAL WORKING-UP THEIR RELEVANT APPARATUS TRANSPORTING
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Zusammenfassung:	本发明涉及多孔有机功能材料领域，提供了一种双吡啶基多孔有机笼、笼衍生的共价有机框架及应用，采用了BPDDP作为合成子，环己二胺，联苯胺和5,5'-二氨基-2,2'-联吡啶分别作为连接体合成了BPPOC以USTB-1和USTB-2。BPPOC通过亚胺键交换作用，从笼中环己二胺转化为COFs中的联苯胺和5,5'-二氨基-2,2'-联吡啶成功地转化为同结构的USTB-1c和USTB-2c。本发明的BPPOC对碘蒸汽气的吸附量打破了多孔有机笼类材料吸附值的最高记录。与直接合成的USTB-1和USTB-2相比，通过有机笼转化而来的USTB-1c和USTB-2c具有更高的碘蒸汽吸附能力。 The invention relates to the field of porous organic functional materials, and provides a bipyridyl porous organic cage, a cage-derived covalent organic framework and application, BPPOC is synthesized by using BPDDP as a synthon and using cyclohexanediamine, benzidine and 5, 5 '-diamino-2, 2'-dipyridyl as linkers respectively, and USTB-1 and USTB-2 are used as the linkers respectively. BPPOC is converted into benzidine and 5, 5 '-diamino-2, 2'-dipyridyl in COFs (Covalent Organic Frameworks) through an imine bond exchange effect, and the benzidine and the 5, 5 '-diamino-2, 2'-dipyridyl are successfully converted into USTB-1c and USTB-2c with the same structure. The adsorption capacity of the BPPOC on the iodine steam breaks