Bimetal Cu/Zr-MOFs adsorption desulfurizer as well as preparation method and application thereof

The invention discloses a bimetallic Cu/Zr-MOFs adsorption desulfurizer as well as a preparation method and application thereof, and belongs to the technical field of adsorption desulfurization. The preparation method of the bimetallic Cu/Zr-MOFs adsorption desulfurizer comprises the following steps...

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Hauptverfasser:	HUO QUAN, QI YUMING, LIU SUYAN, SUN HAIHUI, GUO JUNJIE, FAN ZHANPENG, ZHAO JIAYAO, WANG YUANYUAN
Format:	Patent
Sprache:	chi ; eng
Schlagworte:	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY CRACKING HYDROCARBON OILS FUELS LUBRICANTS METALLURGY MINERAL WAXES PEAT PERFORMING OPERATIONS PETROLEUM, GAS OR COKE INDUSTRIES PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE THEIR RELEVANT APPARATUS TRANSPORTING
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Zusammenfassung:	The invention discloses a bimetallic Cu/Zr-MOFs adsorption desulfurizer as well as a preparation method and application thereof, and belongs to the technical field of adsorption desulfurization. The preparation method of the bimetallic Cu/Zr-MOFs adsorption desulfurizer comprises the following steps: firstly, synthesizing MOF-808 (Zr) by using a solvothermal synthesis method; and then the small-grain MOF-808 is organically embedded and connected to the surface of the MOF-199 (Cu) by adopting an internal expansion growth method, so that the bimetallic adsorption desulfurizing agent Cu/Zr-MOFs with the open type core-satellite structure is prepared. The prepared bimetal Cu/Zr-MOFs adsorption desulfurizer has good adsorption desulfurization performance, adsorption equilibrium can be achieved within 120 min, the highest adsorption capacity can reach 56 mg/g, and the adsorbent is simple and environmentally friendly in preparation process and can be recycled. 一种双金属Cu/Zr-MOFs吸附脱硫剂及其制备方法和应用，本发明属于吸附脱硫技术领域。双金属Cu/Zr-MOF