一种7-羟基双甲基全碳螺环香豆素及CL-20的包覆方法
本发明提供了一种7-羟基双甲基全碳螺环香豆素及CL-20的包覆方法，包括：步骤一，7-羟基双甲基全碳螺环香豆素包覆：在反应瓶中按顺序依次加入7-羟基双甲基全碳螺环香豆素化合物、甲醇和MOF-808，搅拌之后，过滤，自然晾干，得到包覆产物MOF-808@香豆素；步骤二，CL-20包覆：按顺序依次加入三聚氰胺甲醛树脂预聚体、甲苯、CL-20以及步骤一制得的MOF-808@香豆素，加入柠檬酸催化剂，超声分散均匀，搅拌进行原位聚合，过滤，自然晾干得到包覆产物，即CL-20包覆产物。MOF-808@香豆素具有两重作用，第一重作用是作为固体荧光标记物质，利于在365nm紫外光照射下准确地直观检测CL-20...
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| description | 本发明提供了一种7-羟基双甲基全碳螺环香豆素及CL-20的包覆方法，包括：步骤一，7-羟基双甲基全碳螺环香豆素包覆：在反应瓶中按顺序依次加入7-羟基双甲基全碳螺环香豆素化合物、甲醇和MOF-808，搅拌之后，过滤，自然晾干，得到包覆产物MOF-808@香豆素；步骤二，CL-20包覆：按顺序依次加入三聚氰胺甲醛树脂预聚体、甲苯、CL-20以及步骤一制得的MOF-808@香豆素，加入柠檬酸催化剂，超声分散均匀，搅拌进行原位聚合，过滤，自然晾干得到包覆产物，即CL-20包覆产物。MOF-808@香豆素具有两重作用，第一重作用是作为固体荧光标记物质，利于在365nm紫外光照射下准确地直观检测CL-20包覆的均匀度；第二重作用是，进一步降低了CL-20包覆产物的感度。
The invention provides a 7-hydroxyl dimethyl all-carbon spirocoumarin and CL-20 coating method, which comprises: 1, 7-hydroxyl dimethyl all-carbon spirocoumarin coating: sequentially adding a 7-hydroxyl dimethyl all-carbon spirocoumarin compound, methanol and MOF-808 into a reaction bottle, stirring, filtering, and naturally airing to obtain a 7-hydroxyl dimethyl all-carbon spirocoumarin coating solution; a coating product MOF-808 [alpha] coumarin is obtained; step two, CL-20 coating: sequentially adding a melamino-formaldehyde resin prepolymer, methylbenzene, CL-20 and the MOF-808 coumarin prepared in the step one, adding a citric acid catalyst, performing ultrasonic dispersion un |
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The invention provides a 7-hydroxyl dimethyl all-carbon spirocoumarin and CL-20 coating method, which comprises: 1, 7-hydroxyl dimethyl all-carbon spirocoumarin coating: sequentially adding a 7-hydroxyl dimethyl all-carbon spirocoumarin compound, methanol and MOF-808 into a reaction bottle, stirring, filtering, and naturally airing to obtain a 7-hydroxyl dimethyl all-carbon spirocoumarin coating solution; a coating product MOF-808 [alpha] coumarin is obtained; step two, CL-20 coating: sequentially adding a melamino-formaldehyde resin prepolymer, methylbenzene, CL-20 and the MOF-808 coumarin prepared in the step one, adding a citric acid catalyst, performing ultrasonic dispersion un</description><language>chi</language><subject>CHEMISTRY ; EXPLOSIVES ; EXPLOSIVES OR THERMIC COMPOSITIONS ; MANUFACTURE THEREOF ; MATCHES ; METALLURGY ; USE OF SINGLE SUBSTANCES AS EXPLOSIVES</subject><creationdate>2022</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20221230&DB=EPODOC&CC=CN&NR=114634392B$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25542,76289</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20221230&DB=EPODOC&CC=CN&NR=114634392B$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><title>一种7-羟基双甲基全碳螺环香豆素及CL-20的包覆方法</title><description>本发明提供了一种7-羟基双甲基全碳螺环香豆素及CL-20的包覆方法，包括：步骤一，7-羟基双甲基全碳螺环香豆素包覆：在反应瓶中按顺序依次加入7-羟基双甲基全碳螺环香豆素化合物、甲醇和MOF-808，搅拌之后，过滤，自然晾干，得到包覆产物MOF-808@香豆素；步骤二，CL-20包覆：按顺序依次加入三聚氰胺甲醛树脂预聚体、甲苯、CL-20以及步骤一制得的MOF-808@香豆素，加入柠檬酸催化剂，超声分散均匀，搅拌进行原位聚合，过滤，自然晾干得到包覆产物，即CL-20包覆产物。MOF-808@香豆素具有两重作用，第一重作用是作为固体荧光标记物质，利于在365nm紫外光照射下准确地直观检测CL-20包覆的均匀度；第二重作用是，进一步降低了CL-20包覆产物的感度。
The invention provides a 7-hydroxyl dimethyl all-carbon spirocoumarin and CL-20 coating method, which comprises: 1, 7-hydroxyl dimethyl all-carbon spirocoumarin coating: sequentially adding a 7-hydroxyl dimethyl all-carbon spirocoumarin compound, methanol and MOF-808 into a reaction bottle, stirring, filtering, and naturally airing to obtain a 7-hydroxyl dimethyl all-carbon spirocoumarin coating solution; a coating product MOF-808 [alpha] coumarin is obtained; step two, CL-20 coating: sequentially adding a melamino-formaldehyde resin prepolymer, methylbenzene, CL-20 and the MOF-808 coumarin prepared in the step one, adding a citric acid catalyst, performing ultrasonic dispersion un</description><subject>CHEMISTRY</subject><subject>EXPLOSIVES</subject><subject>EXPLOSIVES OR THERMIC COMPOSITIONS</subject><subject>MANUFACTURE THEREOF</subject><subject>MATCHES</subject><subject>METALLURGY</subject><subject>USE OF SINGLE SUBSTANCES AS EXPLOSIVES</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2022</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZHB-sqPh-fJec93n--Y_nb_raX_P8ymbQIzWFc8XbX4xb9fzvvUvl818sbHt-ZYFT_u7nH10jQyez2p52tP6Ylnbs2k7n22eysPAmpaYU5zKC6W5GZTcXEOcPXRTC_LjU4sLEpNT81JL4p39DA1NzIxNjC2NnJyMiVIEADR6Rf4</recordid><startdate>20221230</startdate><enddate>20221230</enddate><scope>EVB</scope></search><sort><creationdate>20221230</creationdate><title>一种7-羟基双甲基全碳螺环香豆素及CL-20的包覆方法</title></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_CN114634392BB3</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>chi</language><creationdate>2022</creationdate><topic>CHEMISTRY</topic><topic>EXPLOSIVES</topic><topic>EXPLOSIVES OR THERMIC COMPOSITIONS</topic><topic>MANUFACTURE THEREOF</topic><topic>MATCHES</topic><topic>METALLURGY</topic><topic>USE OF SINGLE SUBSTANCES AS EXPLOSIVES</topic><toplevel>online_resources</toplevel><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>一种7-羟基双甲基全碳螺环香豆素及CL-20的包覆方法</title><date>2022-12-30</date><risdate>2022</risdate><abstract>本发明提供了一种7-羟基双甲基全碳螺环香豆素及CL-20的包覆方法，包括：步骤一，7-羟基双甲基全碳螺环香豆素包覆：在反应瓶中按顺序依次加入7-羟基双甲基全碳螺环香豆素化合物、甲醇和MOF-808，搅拌之后，过滤，自然晾干，得到包覆产物MOF-808@香豆素；步骤二，CL-20包覆：按顺序依次加入三聚氰胺甲醛树脂预聚体、甲苯、CL-20以及步骤一制得的MOF-808@香豆素，加入柠檬酸催化剂，超声分散均匀，搅拌进行原位聚合，过滤，自然晾干得到包覆产物，即CL-20包覆产物。MOF-808@香豆素具有两重作用，第一重作用是作为固体荧光标记物质，利于在365nm紫外光照射下准确地直观检测CL-20包覆的均匀度；第二重作用是，进一步降低了CL-20包覆产物的感度。
The invention provides a 7-hydroxyl dimethyl all-carbon spirocoumarin and CL-20 coating method, which comprises: 1, 7-hydroxyl dimethyl all-carbon spirocoumarin coating: sequentially adding a 7-hydroxyl dimethyl all-carbon spirocoumarin compound, methanol and MOF-808 into a reaction bottle, stirring, filtering, and naturally airing to obtain a 7-hydroxyl dimethyl all-carbon spirocoumarin coating solution; a coating product MOF-808 [alpha] coumarin is obtained; step two, CL-20 coating: sequentially adding a melamino-formaldehyde resin prepolymer, methylbenzene, CL-20 and the MOF-808 coumarin prepared in the step one, adding a citric acid catalyst, performing ultrasonic dispersion un</abstract><oa>free_for_read</oa></addata></record> |
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| title | 一种7-羟基双甲基全碳螺环香豆素及CL-20的包覆方法 |
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