一种7-羟基双甲基全碳螺环香豆素及CL-20的包覆方法

本发明提供了一种7-羟基双甲基全碳螺环香豆素及CL-20的包覆方法，包括：步骤一，7-羟基双甲基全碳螺环香豆素包覆：在反应瓶中按顺序依次加入7-羟基双甲基全碳螺环香豆素化合物、甲醇和MOF-808，搅拌之后，过滤，自然晾干，得到包覆产物MOF-808@香豆素；步骤二，CL-20包覆：按顺序依次加入三聚氰胺甲醛树脂预聚体、甲苯、CL-20以及步骤一制得的MOF-808@香豆素，加入柠檬酸催化剂，超声分散均匀，搅拌进行原位聚合，过滤，自然晾干得到包覆产物，即CL-20包覆产物。MOF-808@香豆素具有两重作用，第一重作用是作为固体荧光标记物质，利于在365nm紫外光照射下准确地直观检测CL-20包覆的均匀度；第二重作用是，进一步降低了CL-20包覆产物的感度。 The invention provides a 7-hydroxyl dimethyl all-carbon spirocoumarin and CL-20 coating method, which comprises: 1, 7-hydroxyl dimethyl all-carbon spirocoumarin coating: sequentially adding a 7-hydroxyl dimethyl all-carbon spirocoumarin compound, methanol and MOF-808 into a reaction bottle, stirring, filtering, and naturally airing to obtain a 7-hydroxyl dimethyl all-carbon spirocoumarin coating solution; a coating product MOF-808 [alpha] coumarin is obtained; step two, CL-20 coating: sequentially adding a melamino-formaldehyde resin prepolymer, methylbenzene, CL-20 and the MOF-808 coumarin prepared in the step one, adding a citric acid catalyst, performing ultrasonic dispersion un