Preparation method of modified single-crystal ultrahigh-nickel quaternary NCMA positive electrode material

The invention provides a preparation method of a modified single-crystal ultrahigh-nickel quaternary NCMA positive electrode material. The preparation method comprises the following steps: (1) uniformly mixing an ultrahigh-nickel precursor, a lithium source and a nano oxide in a mixer; (2) obtaining...

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Hauptverfasser: GONG LIFENG, CHAI GUANPENG, ZHANG WEIWEI, FANG MING, XU YIWEI, SU FANGZHE, ZHOU RENPENG, HAN YUHANG, ZHANG XU, ZHENG HONG, ZENG QILIANG, WANG BO, DENG MING, CAO DONGQIANG, HAO PEIDONG, DING HELEI, CHEN YANFEN, CAO TIANFU, LI XIAOSHENG
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention provides a preparation method of a modified single-crystal ultrahigh-nickel quaternary NCMA positive electrode material. The preparation method comprises the following steps: (1) uniformly mixing an ultrahigh-nickel precursor, a lithium source and a nano oxide in a mixer; (2) obtaining a primary firing material; (3) carrying out jaw breaking, rolling, crushing and sieving on the primarily sintered material obtained in the step (2); (4) uniformly mixing the single-crystal ultrahigh-nickel quaternary NCMA positive electrode material obtained in the step (3) with a strontium source and a tungsten source in a mixer; and (5) carrying out secondary sintering, and screening to obtain the positive electrode material. According to the method, on one hand, multiple low-temperature heat preservation sections are added in the sintering process, the content of residual alkali on the surface of the single-crystal ultrahigh-nickel quaternary NCMA positive electrode material is reduced, the processing performan