Method for supplementing nickel and removing copper in nickel electrolysis production system

The invention discloses a method for supplementing nickel and removing copper in a nickel electrolysis production system, which comprises the following steps of: preparing waste liquid with high copper content and high acid content in the system and nickel anolyte, controlling certain Cu < 2 + &g...

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Bibliographische Detailangaben
Hauptverfasser: ZENG HAILONG, MA LIKUN, ZHANG SUCHAO, LI YUXIA, LAN YUYI, ZHANG JINYONG, YU JINLONG, MA ZHIQING
Format: Patent
Sprache:chi ; eng
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Beschreibung
Zusammenfassung:The invention discloses a method for supplementing nickel and removing copper in a nickel electrolysis production system, which comprises the following steps of: preparing waste liquid with high copper content and high acid content in the system and nickel anolyte, controlling certain Cu < 2 + > and H < + > ion concentration, and pumping into an electrolytic bath which takes nickel sulfide as an anode and a titanium plate as a cathode for reaction; in the electrolysis process, Cu < 2 + > and H < + > ions on the cathode obtain electrons to separate out sponge copper or hydrogen, and nickel in the anode loses electrons and enters the electrolyte in the form of Ni < 2 + >. According to the method, a high-copper solution, a high-acid solution and a low-nickel solution are prepared according to the requirements of copper, nickel and acid in the electrolysis process, the prepared solution is treated through an electrolysis process, and then the low-copper solution, the low-acid solution and the high-nickel solution