Method for preparing lithium phosphate and co-producing basic magnesium carbonate from lithium precipitation mother liquor

A method for preparing lithium phosphate and co-producing basic magnesium carbonate from lithium precipitation mother liquor relates to the technical field of extraction of lithium from brine, and comprises the following steps: heating the lithium precipitation mother liquor: reacting the lithium pr...

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Hauptverfasser: HOU ZHAOFEI, WANG MIAN, PENG HAIWEI, XIE ANFU, ZAN CHAO, TANG FAMAN, LI WENBIN, LIU WEIPING, YUAN LEIMING, MA SHUANGCAI, SONG YONGXIAO, LI ZENGRONG, GUI XIEZHUO, SHI CHENGWEN, ZHENG CHANGSHENG
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:A method for preparing lithium phosphate and co-producing basic magnesium carbonate from lithium precipitation mother liquor relates to the technical field of extraction of lithium from brine, and comprises the following steps: heating the lithium precipitation mother liquor: reacting the lithium precipitation mother liquor and a phosphate solution in a ratio of 0.98:1 at 80-85 DEG C for 1.5-2 hours to obtain slurry containing solid lithium phosphate; separating the slurry to obtain a crude lithium phosphate product, wherein the tail liquid is used as a raw material for producing basic magnesium carbonate; carrying out preliminary acid adjustment on the tail liquid through hydrochloric acid; adjusting the pH of the tail liquid, and mixing the tail liquid with nanofiltration concentrated water according to the volume ratio of 3:1 to generate basic magnesium carbonate; carrying out filter pressing dehydration and washing on the basic magnesium carbonate solution; and carrying out flash evaporation drying on the