METHOD FOR PRODUCING ORGANOPHOSPHORUS COMPOUND

The present invention provides a method for producing an organophosphorus compound. A method for producing R1R2PONa, which comprises a step for reacting R1R2R3P(O) and sodium metal with each other, and which excludes the cases where a liquid ammonia is used as a solvent in the reaction, provided tha...

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Bibliographische Detailangaben
Hauptverfasser: FUJINO HIROYOSHI, HAN LI-BIAO, SHINOHARA HIROYUKI, MINO YUKA, IKAWA EIICHI, MUKAI TAKESHI, KITAMURA YUTO
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The present invention provides a method for producing an organophosphorus compound. A method for producing R1R2PONa, which comprises a step for reacting R1R2R3P(O) and sodium metal with each other, and which excludes the cases where a liquid ammonia is used as a solvent in the reaction, provided that each of R1, R2 and R3 independently represents a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group. Consequently, the present invention provides a novel method for producing an organophosphorus compound. A production method according to the present invention is a safe and inexpensive method since a liquid ammonia is not used as a solvent and a low temperature is not required therefor. According to the present invention, by-products are suppressed in comparison to conventional methods, and a desired reaction proceeds highly selectively. In addition, a desired product is able to be synthesized in a single pot without requiring isolation. 提供有机磷化合物的制造方法。一种R1R2PONa的制造方法,其包括使R1R2R3P(