Method for measuring chemical oxygen demand in high-chlorine wastewater

The invention relates to a method for measuring COD of high-chlorine wastewater by utilizing a TOC analyzer, which comprises the following steps of: 1, drawing a standard curve by taking potassium hydrogen phthalate as a reference reagent and adopting a non-dispersive infrared detection method; 2, c...

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Hauptverfasser: XIA QIUJU, YANG ZHIJUN, WANG CHUAN, ZHAO XIA, WU ZHENGZONG, WANG LINPING, ZHANG CHANGBANG, XIN WENPING, LIU GUOJIAN, ZHOU YING, LI QIAOLIN, CHANG CHONG, LI QIANQIAN, MA PINGLING, YANG JINHUA
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention relates to a method for measuring COD of high-chlorine wastewater by utilizing a TOC analyzer, which comprises the following steps of: 1, drawing a standard curve by taking potassium hydrogen phthalate as a reference reagent and adopting a non-dispersive infrared detection method; 2, cleaning a microsyringe of the TOC analyzer with a high-chlorine wastewater sample; 3, taking a high-chlorine wastewater sample by using a microsyringe, carrying out high-temperature catalytic combustion, and detecting the amount of generated CO2; and 4, calculating the COD value of the high-chlorine wastewater sample according to the standard curve. Serious interference of chloride ions on a detection result can be eliminated, the measurement result is close to a theoretical value, and the accuracy is high; the temperature in the high-temperature combustion tube is uniform by controlling the sample injection amount and temperature, so that chloride salts in a sample are prevented from being gasified to block the co