Alkylation/acylation method of photooxidation reduction/copper co-catalysis

The invention discloses an alkylation/acylation method of photooxidation reduction/copper co-catalysis. According to the invention, the method comprises the steps: taking novel diacyl peroxide as an alkylation/acylation reagent, and introducing different alkyl (secondary alkyl) or acyl (tertiary alkyl) into various different nitrogen-containing nucleophilic reagents under the common catalysis condition of copper catalysis and photooxidation reduction catalysts, wherein the reaction conditions are mild and simple, economy and cheapness are achieved, the yield is excellent, and the reaction substrate adaptability is good. 本发明公开了一种光氧化还原/铜共催化的烷基化/酰基化方法。该方法使用新颖的二酰基过氧化物作为烷基化/酰基化试剂，在铜催化和光氧化还原催化剂的共同催化条件下，对各种不同的含氮亲核试剂引入不同的烷基(仲烷基)或酰基(叔烷基)，反应条件温和简单、经济便宜、产率优异，反应底物适应性好。