Tri(2-furyl)borane-tri(2-maleimidoethyl)amine DA reaction adduct

The invention belongs to the field of synthesis, particularly relates to a tri(2-furyl)borane-tri(2-maleimidoethyl)amine DA reaction adduct, and further provides a preparation method of the adduct. Furan and maleimido are utilized to generate reversible Diels-Alder reaction, and the adduct has a rep...

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Bibliographische Detailangaben
Hauptverfasser: CHEN YALONG, YANG TAO, FAN QI, YANG SHUOBING
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention belongs to the field of synthesis, particularly relates to a tri(2-furyl)borane-tri(2-maleimidoethyl)amine DA reaction adduct, and further provides a preparation method of the adduct. Furan and maleimido are utilized to generate reversible Diels-Alder reaction, and the adduct has a repetitive self-repairing characteristic. According to the invention, the problem of lack of covalent bond materials applicable to the field of PVC is solved, and a reversible material with thermally induced covalent bonds and repetitive self-repairing characteristics is formed by utilizing reversibleDA reaction. 本发明属于合成领域,具体涉及一种三(2-呋喃基)硼烷-三(2-马来酰亚胺基乙基)胺DA反应加成物,利用呋喃和马来酰亚胺基团发生可逆的Diels-Alder反应,且该加成物具有重复性自修复特性,并进一步提供了该加成物的制备方法。本发明解决了适用于PVC领域的共价键材料匮乏的问题,利用可逆的DA反应,形成具备热致共价键,且具有重复性自修复特性的可逆材料。