Polysiloxane functionalized ethylene-norbornene copolymer and preparation method thereof
The invention relates to a polysiloxane functionalized ethylene-norbornene copolymer and preparation method thereof. The structural general formula of the polysiloxane functionalized ethylene-norbornene copolymer is shown as the following formula (I-1) or (I-2), in the formula, R1 is selected from C...
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Zusammenfassung: | The invention relates to a polysiloxane functionalized ethylene-norbornene copolymer and preparation method thereof. The structural general formula of the polysiloxane functionalized ethylene-norbornene copolymer is shown as the following formula (I-1) or (I-2), in the formula, R1 is selected from C1-C8 alkyl, C1-C8 fluorine-containing alkyl or phenyl, and R2 is selected from C1-C8 alkyl; whereinx is a natural number ranging from 100 to 10000, y is a natural number ranging from 10 to 300, and a is a natural number ranging from 3 to 90. The preparation method comprises three steps of hydrosilylation, anionic ring-opening polymerization and coordination copolymerization, and the preparation method avoids the toxic action of the strong polarity of polysiloxane on a transition metal catalystcommonly used in olefin polymerization under the condition of high polysiloxane content; the polysiloxane content and the weight-average molecular weight in the prepared polysiloxane functionalized ethylene norbornene copolyme |
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