Method for synergistically catalyzing oxidization of cycloalkane by using confinement metalloporphyrin manganese (II)/Cu (II) salt

The invention relates to a method for synergistically catalyzing oxidization of cycloalkane by using confinement metalloporphyrin manganese (II)/Cu (II) salt. The method comprises the following steps:dispersing confinement metalloporphyrin manganese (II) (1*10-0.1%, mol/mol) and Cu (II) salt (0.01-10%, mol/mol) in cycloalkane, sealing a reaction system, heating the reaction system to 90-150 DEG C while stirring, introducing an oxidant, keeping the reaction system at a set temperature and a set pressure, carrying out stirring and reacting for 2.0-24.0 hours, and performing post-treatment on a reaction solution to obtain products, namely cycloalkyl alcohol and cycloalkyl ketone. The method disclosed by the invention has the advantages of high selectivity of cycloalkyl alcohol and cycloalkyl ketone, low reaction temperature, few byproducts, small environmental influence and the like. In addition, the content of cycloalkyl hydroperoxide is low, and a safety coefficient is high. The invention provides the effi