Method for synergistically catalyzing oxidization of cycloalkane by using confinement metalloporphyrin cobalt (II)/Zn (II) salt

The invention provides a method for synergistically catalyzing oxidization of cycloalkane by using confinement metalloporphyrin cobalt (II)/Zn (II) salt. The method comprises the following steps: dispersing confinement metalloporphyrin cobalt (II) (0.001%-5%, g/mol) and Zn (II) salt (0.01%-10%, mol/mol) into cycloalkane, sealing a reaction system, carrying out heating to 90-150 DEG C while stirring, introducing an oxidant, keeping the reaction system at a set temperature and aset pressure, conducting stirring and reacting for 2.0-24.0 hours, and carrying out aftertreatment on a reaction solution to obtain products, namely cycloalkyl alcohol and cycloalkyl ketone. The method provided by the invention has the advantages of high naphthenic alcohol and naphthenic ketone selectivity, low reaction temperature, few byproducts, small environmental influence and the like. In addition; the content of cycloalkyl hydroperoxide is low; and a safety coefficient is high. The invention provides the efficient; feasible and sa