Deprotonated beta-ketimine lithium compound and preparation method thereof

The invention relates to a lithium compound and a preparation method thereof, in particular to a deprotonated beta-ketimine lithium compound and a preparation method thereof. The preparation method comprises the following steps: taking m-phenylenediamine and acetylacetone as raw materials to react t...

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Bibliographische Detailangaben
Hauptverfasser: ZHOU SHUAI, CAI LINGXIA, XUE MINGQIANG, KANG ZIHAN, ZHENG YU, XU XIAOJUAN
Format: Patent
Sprache:chi ; eng
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Beschreibung
Zusammenfassung:The invention relates to a lithium compound and a preparation method thereof, in particular to a deprotonated beta-ketimine lithium compound and a preparation method thereof. The preparation method comprises the following steps: taking m-phenylenediamine and acetylacetone as raw materials to react to prepare a ligand, mixing a small molecular organic lithium solution with a ligand solution, and then reacting to obtain the deprotonated beta-ketimine lithium compound. The technical prejudice that the method in the prior art focuses on complexes with single negative ion beta-ketimine as a skeleton is overcome, the double negative ion beta-ketimino complex is disclosed for the first time, and the blank in the prior art is filled. 本发明涉及一种锂化合物及其制备方法,具体涉及一种脱质子β-酮亚胺锂化合物及其制备方法。以间苯二胺、乙酰丙酮为原料反应制备配体,将小分子有机锂溶液与配体溶液混合,然后反应,得到脱质子β-酮亚胺锂化合物。本发明克服了现有技术都集中在单负离子β-酮亚胺为骨架的配合物的技术偏见,首次公开了双负离子β-酮亚胺基配合物,填补了现有技术空白。