Radiation cooling film and preparation method and application thereof

The invention discloses a radiation cooling film which is formed by mixing ceramic particles, an organic solution and a curing agent, mixing the ceramic particles with an organic curing precursor solution, and curing, a micro-nano photon structure array is formed on the surface of the film, and the micro-nano photon structure array comprises a plurality of arrayed micro-nano photon structure elements. The invention further discloses a preparation method and application of the radiation cooling film. The film has the reflectivity of 95% in the sunlight band and the radiance of 96% in the atmospheric window band, can be lower than the ambient environment by 10 DEG C at most under the illumination condition, and also has good flexibility and strength and excellent hydrophobicity. The radiation cooling film is prepared in a low-cost and large-area manner by adopting a multi-etching double-spin-coating vacuum thermocuring process. The radiation cooling film is applied to the aspects of human body wearable cooling,