Aliphatic tertiary amine functionalized zirconium-based metal organic framework material and preparation method thereof

The invention belongs to the technical field of metal organic synthesis, and particularly relates to an aliphatic tertiary amine functionalized zirconium-based metal organic framework material and a preparation method thereof. The preparation method comprises the following steps: firstly, taking a formyl pre-functionalized organic ligand and an inorganic metal salt as raw materials, preparing a formyl functionalized zirconium-based metal organic framework material by adopting a solvothermal method under an acidic condition, soaking a formyl functionalized material in a corresponding formamideorganic compound, taking formic acid as a reducing agent, and preparing the corresponding aliphatic tertiary amine functionalized metal organic framework material through reductive amination at enoughtemperature. The tertiary amine functionalized zirconium-based metal organic framework material is obtained through reaction, the used method is simple in synthesis, raw materials are easy to obtain,large-scale preparation is