Synthesis method for organic-metal catalyst and application of organic-metal catalyst in MPV reaction
The invention discloses a synthesis method for an organic-metal catalyst and an application of the organic-metal catalyst in an MPV reaction and belongs to the technical field of catalytic conversionof biomass. According to the catalyst prepared by the method, the synthesis steps are simple, used ra...
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Format: | Patent |
Sprache: | chi ; eng |
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Zusammenfassung: | The invention discloses a synthesis method for an organic-metal catalyst and an application of the organic-metal catalyst in an MPV reaction and belongs to the technical field of catalytic conversionof biomass. According to the catalyst prepared by the method, the synthesis steps are simple, used raw materials are cheap and readily available, and the obtained catalyst carries a large number of Lewis acid acidic loci and alkaline loci, and thus, carbonyl compounds including furfural, n-nonaldehyde, 2-hexanone, cyclohexanone, propylethanone or levulinate and corresponding alcohol can be efficiently catalyzed. According to the synthesis method and the application, the catalyst is easy to separate after the catalyst reacts, the catalyst can be reused, and thus, the synthesis method is in linewith requirements on environment-friendly sustainable development.
本发明公开了有机-金属催化剂的合成方法及其在MPV反应中的应用,属于生物质催化转化技术领域。本发明所制备的催化剂合成步骤简单,所使用到的原料廉价易得,得到的催化剂自身携带大量的路易斯酸酸性位点以及碱性位点,能高效催化羰基化合物包括糠醛、正壬醛、2-己酮、环己酮、丙乙酮或乙酰丙酸酯类到相应的醇。本申请中催化剂反应后催 |
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