Polypropylene random copolymer and preparation method thereof

The invention provides a polypropylene random copolymer and a preparation method thereof. The preparation method of the polypropylene random copolymer comprises the following steps: 1) adding a prepolymerization catalyst, a cocatalyst and a modifier into a first gas phase reactor, introducing propyl...

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Hauptverfasser: QIN JUN, FENG KAI, WU LIPING, HU TINGFANG, MA JIN, TIAN QICHAO, MA GENG, ZHAO JINGCAO, CHEN JIGUO, ZHAO ZE, ZHU JUN, XI JUN, FENG HONGWEI, ZHOU WEIXIN, HU BIN
Format: Patent
Sprache:chi ; eng
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Zusammenfassung:The invention provides a polypropylene random copolymer and a preparation method thereof. The preparation method of the polypropylene random copolymer comprises the following steps: 1) adding a prepolymerization catalyst, a cocatalyst and a modifier into a first gas phase reactor, introducing propylene, ethylene and hydrogen into the first gas phase reactor, and carrying out a first polymerizationreaction to obtain a first polymerization reaction mixture; 2) separating a gas phase in the first polymerization reaction mixture to obtain a solid first polymerization reaction mixture; and 3) adding the solid first polymerization reaction mixture into a second gas phase reactor, introducing propylene, ethylene and hydrogen into the second gas phase reactor, and carrying out a second polymerization reaction to obtain the polypropylene random copolymer, wherein the prepolymerization catalyst is a titanium group catalyst, and the activity of the titanium group catalyst is 13000-30000 g/g. Thepreparation method can be